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Pronounced Ligand Effects and the Role of Formal Oxidation States in the Nickel-Mediated Thermal Activation of Methane

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  • Financial support of this work by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie is acknowledged. We are grateful to a reviewer for valuable comments and suggestions.

Abstract

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Related but different: The thermal activation of methane by cationic nickel complexes depends crucially on the nature of ligands and the formal oxidation state of the metal, as is illustrated by the isomeric water complexes: whereas [Ni(H2O)]+ is unreactive, the NiIII isomer [Ni(H)(OH)]+ activates the C[BOND]H bond in methane.

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