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Keywords:

  • coordination modes;
  • nanostructures;
  • scanning probe microscopy;
  • supramolecular chemistry;
  • tectons
Thumbnail image of graphical abstract

Nanopatterning of multifunctional architectures, that is, 1D or 2D arrays on surfaces, can be achieved through bottom-up fabrication of 1D coordination networks by self-assembly processes. A coordinating tecton bearing both monodentate and tridentate coordination poles is combined with suitable metal centers (see scanning tunneling microscopy image).