SEARCH

SEARCH BY CITATION

Keywords:

  • crystal-field parameters;
  • electron transfer;
  • metastable states;
  • Prussian blue analogues;
  • X-ray absorption spectroscopy
Thumbnail image of graphical abstract

Light influence: The Co crystal-field parameter was used as a probe of the photoinduced metastable state of a RbCoFe Prussian blue analogue. From the light-induced change in this parameter, a scheme of the photoinduced structural rearrangement is proposed in which cooperative interactions within the three-dimensional structure impose linear geometry on all Co-NC-Fe entities in the metastable state (see picture).