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Keywords:

  • DNA;
  • polyelectrolytes;
  • porosity;
  • redox chemistry;
  • self-assembly
Thumbnail image of graphical abstract

Bottoms up! Films were built up in a layer-by-layer fashion using high-molar-mass double-stranded DNA and cationic poly(ferrocenylsilane) polyelectrolytes. In this one-step “bottom-up” self-assembly approach, a unique macroporous architecture (see picture) featuring biocompatible and redox-active components was obtained.