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Keywords:

  • atomic force microscopy;
  • nanotechnology;
  • polymers;
  • single‒molecule studies;
  • supramolecular chemistry
Thumbnail image of graphical abstract

The power of the Force: The rupture force of supramolecular bonds, as well as the unbinding dynamics of associated polymers, have been studied by AFM-based single-molecule force spectroscopy (AFM-SMFS). The first quantitative comparison of bond-rupture dynamics from independent AFM-SMFS and NMR data is highlighted.