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Keywords:

  • molecular wires;
  • nanostructures;
  • porphyrinoids;
  • self-assembly;
  • template synthesis

Graphical Abstract

Thumbnail image of graphical abstract

Round the bend: Bending a molecular wire round an eight-spoked template leads to the formation of a highly symmetric belt-shaped π system (green in picture). Addition of a large excess of pyridine releases the corresponding cyclic octamer from the template.