Support by the DFG (Emmy Noether-Programm), the Spanish Ministerio de Educación y Ciencia (fellowship for P.A.B.), the Fonds der Chemischen Industrie, the Dr. Otto Röhm Gedächtnisstiftung, the Römer Foundation, and Sanofi-Aventis (Frankfurt) is gratefully acknowledged.
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Communication
Ruthenium(IV) Alkylidenes as Precatalysts for Direct Arylations of Alkenes with Aryl Chlorides and an Application to Sequential Catalysis†
Article first published online: 19 JUL 2007
DOI: 10.1002/anie.200701727
Copyright © 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Ackermann, L., Born, R. and Álvarez-Bercedo, P. (2007), Ruthenium(IV) Alkylidenes as Precatalysts for Direct Arylations of Alkenes with Aryl Chlorides and an Application to Sequential Catalysis. Angewandte Chemie International Edition, 46: 6364–6367. doi: 10.1002/anie.200701727
- †
Publication History
- Issue published online: 13 AUG 2007
- Article first published online: 19 JUL 2007
- Manuscript Received: 18 APR 2007
Funded by
- DFG
- Fonds der Chemischen Industrie
- Dr. Otto Röhm Gedächtnisstiftung
- Römer Foundation
- Sanofi-Aventis
Keywords:
- alkenes;
- C
![[BOND]](http://onlinelibrarystatic.wiley.com/undisplayable_characters/00f8ff.gif)
H activation; - hydrosilylation;
- ruthenium carbenes;
- sequential catalysis
Graphical Abstract
Jack of all trades? A ruthenium(IV) carbene complex catalyzes the diastereoselective direct arylation of alkenes using aryl chlorides with high efficiency, which sets the stage for the development of a direct arylation–hydrosilylation sequence (see scheme).