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Keywords:

  • cyclic voltammetry;
  • electrochemical oxidation;
  • peroxides;
  • small ring systems;
  • titanium
Thumbnail image of graphical abstract

Electrical synthesizer: Results of cyclic voltammetric studies on a range of aminocyclopropanes in the absence or in the presence of oxygen are in full agreement with the currently accepted autocatalytic mechanism for the aerobic oxidation of these compounds. A simple and efficient procedure was developed for the electrosynthesis of the corresponding endoperoxides (see scheme), some of which exhibit moderate antimalarial activity.