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Coordination Copolymerization of Polar Vinyl Monomers H2C[DOUBLE BOND]CHX

Authors


  • S.M. is indebted to the Fonds der Chemischen Industrie.

Abstract

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Rising to the challenge: Neutral phosphinosulfonate PdII complexes were recently demonstrated to be versatile catalysts even for the challenging insertion copolymerization of polar functionalized vinyl comonomers H2C[DOUBLE BOND]CHX, such as acrylonitrile, vinyl acetate, and alkyl vinyl ethers (see scheme, MA=methyl acrylate).

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