Communication

A Self-Assembled Spin Cage

  1. Koji Nakabayashi,
  2. Yusuke Ozaki,
  3. Masaki Kawano Dr.,
  4. Makoto Fujita Prof. Dr.

Article first published online: 7 FEB 2008

DOI: 10.1002/anie.200704924

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 47, Issue 11, pages 2046–2048, February 28, 2008

Additional Information

How to Cite

Nakabayashi, K., Ozaki, Y., Kawano, M. and Fujita, M. (2008), A Self-Assembled Spin Cage. Angew. Chem. Int. Ed., 47: 2046–2048. doi: 10.1002/anie.200704924

Author Information

  1. Department of Applied Chemistry, School of Engineering, The University of Tokyo and CREST, Japan Science and Technology Agency (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7257

Publication History

  1. Issue published online: 22 FEB 2008
  2. Article first published online: 7 FEB 2008
  3. Manuscript Received: 24 OCT 2007

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Keywords:

  • host–guest systems;
  • molecular recognition;
  • palladium;
  • radicals;
  • self-assembly
Thumbnail image of graphical abstract

Going for a spin: The quantitative self-assembly of a verdazyl radical-cored ligand with [Pd(bpy)(NO3)2] (bpy=2,2′-bipyridyl) generates a large M6L4 spin cage in which multiple spin centers effectively surround the cavity. The inclusion of a radical guest within the cavity induces spin–spin interactions between the host and the guest.

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