Communication

Highly Conductive Supramolecular Nanostructures of a Covalently Linked Phthalocyanine–C60 Fullerene Conjugate†

  1. Giovanni Bottari Dr.3,
  2. David Olea Dr.2,
  3. Cristina Gómez-Navarro Dr.2,
  4. Felix Zamora Dr.1,
  5. Julio Gómez-Herrero Dr.2,
  6. Tomás Torres Prof.3

Article first published online: 6 FEB 2008

DOI: 10.1002/anie.200705260

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 47, Issue 11, pages 2026–2031, February 28, 2008

Additional Information

How to Cite

Bottari, G., Olea, D., Gómez-Navarro, C., Zamora, F., Gómez-Herrero, J. and Torres, T. (2008), Highly Conductive Supramolecular Nanostructures of a Covalently Linked Phthalocyanine–C60 Fullerene Conjugate. Angew. Chem. Int. Ed., 47: 2026–2031. doi: 10.1002/anie.200705260

Author Information

  1. 1

    Departamento de Química Inorgánica, Universidad Autónoma de Madrid, Cantoblanco 28049 Madrid, Spain, Fax: (+34) 91-497-3962

  2. 2

    Departamento de Física de la Materia Condensada, Universidad Autónoma de Madrid, Cantoblanco 28049 Madrid, Spain, Fax: (+34) 91-497-3015

  3. 3

    Departamento de Química Orgánica, Universidad Autónoma de Madrid, Cantoblanco 28049 Madrid, Spain, Fax: (+34) -91-497-3966 http://www.uam.es/phthalocyanines

  1. †

    Financial support by the MEC (Spain) (grants CTQ2005-08933/BQU, MAT2004-05589-C02-01/02, NAN2004-09183-C10-05/06, and CONSOLIDER-INGENIO 2010 CSD2007-0010 NANOCIENCIA MOLECULAR), Comunidad de Madrid (Spain) (grants S-0505/PPQ/000225 and S-0505/MAT/0303), and European Union (MRTN CT-2006-035533 and FP6-029192) is gratefully acknowledged. G.B. and D.O. thank the Spanish MEC for a “Ramón y Cajal” and a “Juan de la Cierva” contract, respectively.

Publication History

  1. Issue published online: 22 FEB 2008
  2. Article first published online: 6 FEB 2008
  3. Manuscript Received: 15 NOV 2007

Funded by

  • MEC (Spain). Grant Numbers: CTQ2005-08933/BQU, MAT2004-05589-C02-01/02, NAN2004-09183-C10-05/06
  • CONSOLIDER-INGENIO. Grant Number: 2010 CSD2007-0010 NANOCIENCIA MOLECULAR
  • Comunidad de Madrid (Spain). Grant Numbers: S-0505/PPQ/000225, S-0505/MAT/0303
  • European Union. Grant Numbers: MRTN CT-2006-035533, FP6-029192

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Keywords:

  • conducting materials;
  • fullerenes;
  • nanostructures;
  • phthalocyanines;
  • self-assembly
Thumbnail image of graphical abstract

Conducting surfaces: A covalently linked phthalocyanine–C60 fullerene conjugate 1 (see picture) is able to self-organize on graphite and graphite-like surfaces, thus giving rise to supramolecular fibers and films. These nanostructures are electrically characterized by conductive atomic force microscopy and show outstanding nanoscale electrical conductivity.

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