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A Crystallizable f-Element Tuck-In Complex: The Tuck-in Tuck-over Uranium Metallocene [(C5Me5)U{μ-η5:η1:η1-C5Me3(CH2)2}(μ-H)2U(C5Me5)2]†

  1. William J. Evans Prof.1,
  2. Kevin A. Miller1,
  3. Antonio G. DiPasquale Dr.2,
  4. Arnold L. Rheingold Prof.2,
  5. Timothy J. Stewart3,
  6. Robert Bau Prof.3

Article first published online: 27 MAY 2008

DOI: 10.1002/anie.200801062

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 47, Issue 27, pages 5075–5078, June 23, 2008

Additional Information

How to Cite

Evans, William J., Miller, Kevin A., DiPasquale, Antonio G., Rheingold, Arnold L., Stewart, Timothy J. and Bau, R. (2008), A Crystallizable f-Element Tuck-In Complex: The Tuck-in Tuck-over Uranium Metallocene [(C5Me5)U{μ-η5:η1:η1-C5Me3(CH2)2}(μ-H)2U(C5Me5)2]. Angew. Chem. Int. Ed., 47: 5075–5078. doi: 10.1002/anie.200801062

Author Information

  1. 1

    Department of Chemistry, University of California, Irvine, CA 92697-2025 (USA), Fax: (+1) 949-824-2210

  2. 2

    Department of Chemistry and Biochemistry, University of California, San Diego, CA 92093-0358 (USA)

  3. 3

    Department of Chemistry, University of Southern California, Los Angeles, CA 90089 (USA)

  1. †

    We thank the Chemical Sciences, Geosciences, and Biosciences Division of the Office of Basic Energy Sciences of the Department of Energy for support.

Publication History

  1. Issue published online: 16 JUN 2008
  2. Article first published online: 27 MAY 2008
  3. Manuscript Received: 5 MAR 2008

Funded by

  • Chemical Sciences, Geosciences, and Biosciences Division of the Office of Basic Energy Sciences of the Department of Energy

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Keywords:

  • actinides;
  • coordination modes;
  • cyclopentadienyl ligands;
  • hydrides;
  • uranium
Thumbnail image of graphical abstract

Long sought structural data on an f-element tuck-in complex have been obtained for the title compound 1 that contains the first example of both tuck-in and tuck-over bonding in a ligand derived from C5Me5− by metalation (see scheme).

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