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Keywords:

  • dehydrocoupling;
  • hydrogen storage;
  • inorganic polymers;
  • iridium;
  • polyaminoboranes
Thumbnail image of graphical abstract

The B all and N all: Soluble, linear, high molecular weight polyaminoborane homopolymers and copolymers have been synthesized by iridium-catalyzed dehydrocoupling of readily available amine–borane adducts RNH2⋅BH3 (R=H, Me, nBu).