This work was supported by the Deutsche Forschungsgemeinschaft, Bonn, within the frameworks of the SFB 608 and the SPP 1166.
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Superbulky Ligands and Trapped Electrons: New Perspectives in Divalent Lanthanide Chemistry†
Article first published online: 26 MAY 2008
DOI: 10.1002/anie.200801444
Copyright © 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
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How to Cite
Meyer, G. (2008), Superbulky Ligands and Trapped Electrons: New Perspectives in Divalent Lanthanide Chemistry. Angew. Chem. Int. Ed., 47: 4962–4964. doi: 10.1002/anie.200801444
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Publication History
- Issue published online: 16 JUN 2008
- Article first published online: 26 MAY 2008
Funded by
- Deutsche Forschungsgemeinschaft. Grant Numbers: SFB 608, SPP 1166
- Abstract
- Article
- References
- Cited By
Keywords:
- electron localization;
- lanthanides;
- lanthanum;
- samarium;
- superbulky ligands
Spectacular developments in recent years, especially the discovery of an anionic complex of divalent lanthanum, in which the electron is trapped in a localized 5d1 SOMO (see structure of the anion of [K([2.2.2]crypt)][LaCp′′3] (Cp′′=1,3-(SiMe3)2C5H3); La red, C gray, Si black), have brought new impetus to the solution chemistry of divalent lanthanides.