Combining the Concepts: Dual Catalysis with Carbophilic Lewis Acids

Authors


  • Research at Technische Universität München has been supported by the Fonds der Chemischen Industrie and DFG (Deutsche Forschungsgemeinschaft). We thank Prof. Thorsten Bach and his group for generous support.

Abstract

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Strong together: Both a gold complex and a palladium complex are needed as catalysts in a Stille-type reaction that does not require an organic halide for the oxidative-addition step (see scheme; dba=trans,trans-dibenzylideneacetone). The bimetallic catalyst system facilitates the construction of highly substituted olefins. Additional examples of reactions that employ the combined action of a π acid and a cocatalyst are briefly discussed.

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