This work was supported by the JSPS (19760541) and the Global COE Program for Chemistry Innovation.
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Communication
Cooperative Catalysis of Primary and Tertiary Amines Immobilized on Oxide Surfaces for One-Pot C![[BOND]](http://onlinelibrarystatic.wiley.com/undisplayable_characters/00f8ff.gif)
C Bond Forming Reactions†
Article first published online: 2 SEP 2008
DOI: 10.1002/anie.200802515
Copyright © 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Issue
Angewandte Chemie International Edition
Volume 47, Issue 48, pages 9230–9235, November 17, 2008
Additional Information
How to Cite
Motokura, K., Tada, M. and Iwasawa, Y. (2008), Cooperative Catalysis of Primary and Tertiary Amines Immobilized on Oxide Surfaces for One-Pot CC Bond Forming Reactions. Angew. Chem. Int. Ed., 47: 9230–9235. doi: 10.1002/anie.200802515
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Publication History
- Issue published online: 12 NOV 2008
- Article first published online: 2 SEP 2008
- Manuscript Revised: 25 JUL 2008
- Manuscript Received: 29 MAY 2008
Funded by
- JSPS. Grant Number: 19760541
- Global COE Program for Chemistry Innovation
Keywords:
- CC coupling;
- cooperative effects;
- immobilization;
- nitroalkanes;
- supported catalysts
D'you know what amine? Primary and tertiary amines are both immobilized on the same silica–alumina surface by silane-coupling reactions. The resultant silica–alumina-supported double-amines are found to exhibit excellent catalysis for 1,3-dinitroalkane synthesis from various aldehydes with nitromethane. A cooperative catalytic mechanism on the solid surface for this efficient synthesis is proposed.