This work was supported by a W.M. Keck Foundation grant to establish the Keck Institute for Attofluidic Nanotube-Based Probes at Drexel University. The authors would like to thank J. Giammarco for producing carbon nanotubes, T. Farouk, B. Farouk (all Drexel University), and J.E. Fischer (University of Pennsylvania) for helpful discussions.
Communication
Nanoscale Corona Discharge in Liquids, Enabling Nanosecond Optical Emission Spectroscopy†
Article first published online: 29 AUG 2008
DOI: 10.1002/anie.200802891
Copyright © 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Staack, D., Fridman, A., Gutsol, A., Gogotsi, Y. and Friedman, G. (2008), Nanoscale Corona Discharge in Liquids, Enabling Nanosecond Optical Emission Spectroscopy. Angew. Chem. Int. Ed., 47: 8020–8024. doi: 10.1002/anie.200802891
- †
Publication History
- Issue published online: 29 SEP 2008
- Article first published online: 29 AUG 2008
- Manuscript Received: 17 JUN 2008
Funded by
- W.M. Keck Foundation
Keywords:
- emission spectroscopy;
- optical analysis;
- plasma chemistry;
- trace analysis

My corona! A nonthermal corona discharge inside a liquid medium around electrodes with ultrasharp tips or elongated nanoparticles allows simultaneous chemical analysis of multiple dissolved elements within nanoseconds. The proposed optical emission spectroscopy method can be applied for ultrafast time-resolved multielemental analysis of femtoliter volumes of liquid with a one-micrometer spatial resolution.

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