Scientific advice by Jacco van Beek, René Verel, and Urban Meier and financial support by the Schweizerischer Nationalfonds, the ETH Zurich, and the Kommission für Technologie und Innovation is acknowledged.
One- and Two-Dimensional NMR Spectroscopy with a Magnetic-Resonance Force Microscope†
Article first published online: 16 OCT 2008
Copyright © 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Angewandte Chemie International Edition
Volume 47, Issue 46, pages 8961–8963, November 3, 2008
How to Cite
Eberhardt, Kai W., Degen, Christian L., Hunkeler, A. and Meier, Beat H. (2008), One- and Two-Dimensional NMR Spectroscopy with a Magnetic-Resonance Force Microscope. Angew. Chem. Int. Ed., 47: 8961–8963. doi: 10.1002/anie.200802978
- Issue published online: 28 OCT 2008
- Article first published online: 16 OCT 2008
- Manuscript Received: 21 JUN 2008
- Schweizerischer Nationalfonds
- ETH Zurich
- Kommission für Technologie und Innovation
- NMR spectroscopy
At the micrometer scale: Chemical interactions at the atomic level have been characterized with localized spectroscopy by using magnetic-resonance force microscopy to locate slices of 2.0 μm thickness in a heterogeneous sample (see picture). To recover the chemical-shift information, the field gradient was temporarily switched off by removing its source mechanically. This technique allows high-resolution one- and two-dimensional NMR spectra to be recorded.