U.K. thanks Jacobs University and ExxonMobil for research support. This work was also supported by the CNRS (UMR 8000) and the Université Paris-Sud 11.
Self-Assembly of a Heteropolyoxopalladate Nanocube: [PdII13AsV8O34(OH)6]8−†
Article first published online: 10 OCT 2008
Copyright © 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Angewandte Chemie International Edition
Volume 47, Issue 49, pages 9542–9546, November 24, 2008
How to Cite
Chubarova, Elena V., Dickman, Michael H., Keita, B., Nadjo, L., Miserque, F., Mifsud, M., Arends, Isabel W. C. E. and Kortz, U. (2008), Self-Assembly of a Heteropolyoxopalladate Nanocube: [PdII13AsV8O34(OH)6]8−. Angew. Chem. Int. Ed., 47: 9542–9546. doi: 10.1002/anie.200803527
- Issue published online: 20 NOV 2008
- Article first published online: 10 OCT 2008
- Manuscript Received: 20 JUL 2008
- Jacobs University
- CNRS. Grant Number: UMR 8000
- Université Paris-Sud 11
- oxidation catalysis;
Not like the others: A molecular palladium oxide cluster was formed by self-assembly of palladium(II) and arsenic(V) using mild reaction conditions. The resulting heteropolypalladate [PdII13AsV8O34(OH)6]8− has a distorted cubic shape and edge lengths of about 1 nm. The thirteen PdII ions retain four-coordinate square-planar geometry, in marked contrast to all other known discrete polyoxometalates.