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Keywords:

  • C[BOND]H activation;
  • direct arylation;
  • heteroarenes;
  • palladium;
  • sulfonates
Thumbnail image of graphical abstract

A toss up: A highly active palladium complex enabled the first direct arylation of heteroarenes through C[BOND]H bond functionalization using tosylates or mesylates as electrophiles with ample scope.