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Keywords:

  • cyclodehydrogenation;
  • fullerenes;
  • heterocycles;
  • heterogeneous catalysis;
  • scanning probe microscopy
Thumbnail image of graphical abstract

Fullerenes made to order: The ability of catalytic surfaces to stitch together the arms of polycyclic aromatic hydrocarbons and heterocycles to form fullerenes and heterofullerenes has been demonstrated. This ability may provide wide-ranging access to tailor-made fullerenes, with the specific arrangements of rings and heteroatoms dictated by the design and synthesis of the precursors.