Communication

Heterogeneously Hybridized Porous Coordination Polymer Crystals: Fabrication of Heterometallic Core–Shell Single Crystals with an In-Plane Rotational Epitaxial Relationship†

  1. Shuhei Furukawa Dr.1,2,
  2. Kenji Hirai3,
  3. Keiji Nakagawa3,
  4. Yohei Takashima3,
  5. Ryotaro Matsuda Dr.1,2,
  6. Takaaki Tsuruoka Dr.1,
  7. Mio Kondo Dr.2,
  8. Rie Haruki Dr.4,
  9. Daisuke Tanaka Dr.3,
  10. Hirotoshi Sakamoto3,
  11. Satoru Shimomura3,
  12. Osami Sakata Dr.4,
  13. Susumu Kitagawa Prof.1,2,3

Article first published online: 12 DEC 2008

DOI: 10.1002/anie.200804836

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 48, Issue 10, pages 1766–1770, February 23, 2009

Additional Information

How to Cite

Furukawa, S., Hirai, K., Nakagawa, K., Takashima, Y., Matsuda, R., Tsuruoka, T., Kondo, M., Haruki, R., Tanaka, D., Sakamoto, H., Shimomura, S., Sakata, O. and Kitagawa, S. (2009), Heterogeneously Hybridized Porous Coordination Polymer Crystals: Fabrication of Heterometallic Core–Shell Single Crystals with an In-Plane Rotational Epitaxial Relationship. Angew. Chem. Int. Ed., 48: 1766–1770. doi: 10.1002/anie.200804836

Author Information

  1. 1

    ERATO Kitagawa Integrated Pores Project (Japan), Kyoto Research Park Bldg #3, Shimogyo-ku, Kyoto 600-8815 (Japan), Fax: (+81) 75-325-3572 http://kip.jst.go.jp

  2. 2

    Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501 (Japan)

  3. 3

    Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)

  4. 4

    Research & Utilization Division (Japan), Synchrotron Radiation Research Institute/SPring-8 and CREST, JST, Kouto, Sayo, Hyogo 679-5198 (Japan)

  1. †

    The synchrotron X-ray diffraction experiments were performed at BL13XU in the SPring-8 with the approval of the JASRI (Proposal No. 2007A1825, 2007B1771, and 2008A1574).

Publication History

  1. Issue published online: 17 FEB 2009
  2. Article first published online: 12 DEC 2008
  3. Manuscript Received: 3 OCT 2008

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Keywords:

  • coordination polymers;
  • crystal growth;
  • interfaces;
  • metal–organic frameworks;
  • microporous materials

Abstract

Thumbnail image of graphical abstract

MOF on MOF: Core–shell porous coordination polymer (PCP) crystals are fabricated at the single-crystal level by epitaxial growth in solution. Synchrotron X-ray diffraction measurements unveiled the structural relationship between the shell crystal and the core crystal, where in-plane rotational epitaxial growth compensates the difference in lattice constant.

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