A Luminescent Microporous Metal–Organic Framework for the Fast and Reversible Detection of High Explosives

Authors


  • A.L. and K.L. contributed equally to this project. A.L. is currently a visiting scholar supported by the CAS/SAFEA International Partnership Program for Creative Research Teams for his research at Rutgers University. We are grateful for the financial support from the DOE (Grant No. DE-FG02-08ER46491).

Abstract

Sensors and sensitivity: A highly luminescent microporous metal–organic framework, [Zn2(bpdc)2(bpee)] (bpdc=4,4′-biphenyldicarboxylate; bpee=1,2-bipyridylethene), is capable of very fast and reversible detection of the vapors of the nitroaromatic explosive 2,4-dinitrotoluene and the plastic explosive taggant 2,3-dimethyl-2,3-dinitrobutane, through redox fluorescence quenching with unprecedented sensitivity (see spectra).

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