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The Inverted Bond in [1.1.1]Propellane is a Charge-Shift Bond^†

Wei Wu Prof.¹,
Junjing Gu¹,
Jinshuai Song¹,
Sason Shaik Prof.²,
Philippe C. Hiberty Prof.³

Article first published online: 15 DEC 2008

DOI: 10.1002/anie.200804965

Issue

Angewandte Chemie International Edition

Volume 48, Issue 8, pages 1407–1410, February 9, 2009

Additional Information

How to Cite

Wu, W., Gu, J., Song, J., Shaik, S. and Hiberty, Philippe C. (2009), The Inverted Bond in [1.1.1]Propellane is a Charge-Shift Bond. Angew. Chem. Int. Ed., 48: 1407–1410. doi: 10.1002/anie.200804965

Author Information

¹
State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (P.R. China), Fax: (+86) 592-218-4708
²
Institute of Chemistry and The Lise Meitner-Minerva Center for Computational Quantum Chemistry, The Hebrew University, Jerusalem, 91904 (Israel), Fax: (+972) 2-658-4680
³
Laboratoire de Chimie Physique, Groupe de Chimie Théorique, CNRS UMR 8000, Université de Paris-Sud, 91405 Orsay Cédex (France), Fax: (+33) 1-6941-6175

Email: Wei Wu Prof. (weiwu@xmu.edu.cn), Sason Shaik Prof. (sason.shaik@gmail.com), Philippe C. Hiberty Prof. (philippe.hiberty@u-psud.fr)

^†
The research in Xiamen is supported by the Natural Science Foundation of China (No 20533020, 20873106) and the National Basic Research Program of China (204CB719902). S.S. is supported by an ISF grant (16/06)

Publication History

Issue published online: 30 JAN 2009
Article first published online: 15 DEC 2008
Manuscript Received: 10 OCT 2008

Funded by

Natural Science Foundation of China. Grant Numbers: 20533020, 20873106
National Basic Research Program of China. Grant Number: 204CB719902

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We are thankful to one of the referees for inducing us to make this prediction.
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For example, a pentagerma[1.1.1]propellane has been synthesized: See D. Nied, W. Klopper, F. Breher, Angew. Chem. 2009, 121, 1439; Angew. Chem. Int. Ed. 2009, 48, 1411.

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