We would like to acknowledge the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie for financial support. We also thank Ann-Katrin Jungton (Berlin) for help with the NMR spectra.
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Communication
C![[BOND]](http://onlinelibrarystatic.wiley.com/undisplayable_characters/00f8ff.gif)
F Activation at Rhodium Boryl Complexes: Formation of 2-Fluoroalkyl-1,3,2-Dioxaborolanes by Catalytic Functionalization of Hexafluoropropene†
Article first published online: 29 JAN 2009
DOI: 10.1002/anie.200805041
Copyright © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Issue
Angewandte Chemie International Edition
Volume 48, Issue 10, pages 1818–1822, February 23, 2009
Additional Information
How to Cite
Braun, T., Ahijado Salomon, M., Altenhöner, K., Teltewskoi, M. and Hinze, S. (2009), CF Activation at Rhodium Boryl Complexes: Formation of 2-Fluoroalkyl-1,3,2-Dioxaborolanes by Catalytic Functionalization of Hexafluoropropene. Angew. Chem. Int. Ed., 48: 1818–1822. doi: 10.1002/anie.200805041
- †
Publication History
- Issue published online: 17 FEB 2009
- Article first published online: 29 JAN 2009
- Manuscript Revised: 2 DEC 2008
- Manuscript Received: 15 OCT 2008
Funded by
- Deutsche Forschungsgemeinschaft
- Fonds der Chemischen Industrie
- Abstract
- Article
- References
- Cited By
Keywords:
- boryl compounds;
- borylation;
- CF activation;
- fluorine;
- rhodium
Abstract
Fluorinated building blocks by CF bond cleavage: Catalytic CF activation reactions that give novel dioxaborolanes have been developed (see scheme). The reactions proceed at room temperature, and catalytic intermediates are presumably rhodium hydride and boryl species.