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Keywords:

  • boryl compounds;
  • borylation;
  • C[BOND]F activation;
  • fluorine;
  • rhodium

Abstract

Thumbnail image of graphical abstract

Fluorinated building blocks by C[BOND]F bond cleavage: Catalytic C[BOND]F activation reactions that give novel dioxaborolanes have been developed (see scheme). The reactions proceed at room temperature, and catalytic intermediates are presumably rhodium hydride and boryl species.