Communication

Highly Conductive Films of Layered Ternary Transition-Metal Nitrides†

  1. Hongmei Luo Dr.1,2,
  2. Haiyan Wang Dr.3,
  3. Zhengxing Bi3,
  4. Guifu Zou Dr.1,
  5. T. Mark McCleskey Dr.1,
  6. Anthony K. Burrell Dr.1,
  7. Eve Bauer1,
  8. Marilyn E. Hawley Dr.4,
  9. Yongqiang Wang Dr.4,
  10. Quanxi Jia Dr.1

Article first published online: 14 JAN 2009

DOI: 10.1002/anie.200805394

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 48, Issue 8, pages 1490–1493, February 9, 2009

Additional Information

How to Cite

Luo, H., Wang, H., Bi, Z., Zou, G., McCleskey, T. Mark., Burrell, Anthony K., Bauer, E., Hawley, Marilyn E., Wang, Y. and Jia, Q. (2009), Highly Conductive Films of Layered Ternary Transition-Metal Nitrides. Angew. Chem. Int. Ed., 48: 1490–1493. doi: 10.1002/anie.200805394

Author Information

  1. 1

    Materials Physics and Applications Division, Los Alamos National Laboratory, Los Alamos, NM 87545 (USA), Fax: (+1) 505-665-3164

  2. 2

    Department of Chemical Engineering, New Mexico State University, Las Cruces, NM 88003 (USA)

  3. 3

    Department of Electrical and Computer Engineering, Texas A&M University, College Station, TX 77843 (USA)

  4. 4

    Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, NM 87545 (USA)

  1. †

    We gratefully acknowledge the support of the U.S. Department of Energy (DOE) through the LANL/LDRD Program, the DOE EE-RE Solid State Lighting Program, and the NSF/DMR Ceramic Program (NSF 0709831).

Publication History

  1. Issue published online: 30 JAN 2009
  2. Article first published online: 14 JAN 2009
  3. Manuscript Received: 4 NOV 2008

Funded by

  • U.S. Department of Energy (DOE). Grant Number: NSF 0709831

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Keywords:

  • nitrides;
  • solution deposition;
  • superconductors;
  • thin films

Abstract

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Film studies: Epitaxial films of BaZrN2 (see TEM image) and BaHfN2 are grown by polymer-assisted deposition on SrTiO3 (STO) substrates. The films are phase-pure, allowing the intrinsic physical properties of the ternary nitrides to be studied. From 5 to 300 K, the films exhibit metallic-like resistivity–temperature behavior, with large residual resistivity ratios.

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