Polymer-Mediated Hierarchical and Reversible Emulsion Droplet Assembly

Authors


  • This work was supported by Centre for Materials Discovery and EPSRC (GR/C511794/1). S.P.R. thanks the Royal Society for an Industry Fellowship. The authors thank Hydra Polymers Ltd. and Prof. M. J. Rosseinsky for valuable discussions.

Abstract

Making and breaking: Stable, functional micrometer-sized emulsion droplets can be assembled into various complex macroscopic liquid structures (see picture). The hierarchical assembly process is mediated by interactions between polymeric surfactant molecules located on the droplet surfaces. These interdroplet interactions are reversible, therefore these “engineered emulsions” can be readily disassembled by using a simple pH switch.

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