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Keywords:

  • high-throughput methods;
  • mesoporous materials;
  • metal–organic frameworks;
  • solvothermal synthesis;
  • structure simulation

Abstract

Thumbnail image of graphical abstract

Large, larger, … Replacement of 1,4-benzenedicarboxylate by 2,6-naphthalenedicarboxylate in the MIL-101 structure leads to an isoreticular mesoporous framework containing cages with diameters of 39 and 46 Å. High-throughput methods are employed to determine appropriate reaction conditions. The microcrystalline compound is characterized by molecular simulation techniques, powder X-ray diffraction, N2-sorption, and TEM investigations.