Cover Picture: Reversible Redox Reactions in an Extended Polyoxometalate Framework Solid (Angew. Chem. Int. Ed. 36/2008)
Article first published online: 20 AUG 2008
DOI: 10.1002/anie.200890175
Copyright © 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Ritchie, C., Streb, C., Thiel, J., Mitchell, Scott G., Miras, Haralampos N., Long, D.-L., Boyd, T., Peacock, Robert D., McGlone, T. and Cronin, L. (2008), Cover Picture: Reversible Redox Reactions in an Extended Polyoxometalate Framework Solid (Angew. Chem. Int. Ed. 36/2008). Angew. Chem. Int. Ed., 47: 6727. doi: 10.1002/anie.200890175
Publication History
- Issue published online: 20 AUG 2008
- Article first published online: 20 AUG 2008
Keywords:
- cluster compounds;
- framework materials;
- polyoxometalates;
- redox chemistry;
- self-assembly

Like a revolving door that can easily open, close, and return to the start, the first framework material that can undergo reversible electron-transfer reactions is described by L. Cronin et al. in their Communication on page 6881 ff. The solid contains large pockets in which the redox reagents can reside; the manganese(II)/(III)-containing framework is able to move between these oxidation states and is the first in a new class of redox solids.

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