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Keywords:

  • cluster compounds;
  • decomposition;
  • iridium;
  • time-resolved spectroscopy
Thumbnail image of graphical abstract

The cycle of formation and breakup of iridium clusters from mononuclear iridium diethylene complexes anchored in dealuminated Y zeolite is demonstrated by B. C. Gates and co-worker in their Communication on page 9245 ff. The picture represents the chemistry of cluster formation and breakup (a cycle, as the progress is reversible), with a background of the zeolite cage in which the chemistry takes place.