This work was supported by the National Science Foundation (CHE-0646916), the Welch Foundation (A-1423), and the US Army Medical Research Institute of Chemical Defense.
1521-3773/asset/2002_left.gif?v=1&s=ac6b0d94a94d7ce7a210002b8096b42feffc0bcf)
1521-3773/asset/2002_right.gif?v=1&s=451042aa3415ae3ad0729984d26dee1866aca82e)
Communication
You have free access to this content
Sulfonium Boranes for the Selective Capture of Cyanide Ions in Water†
Article first published online: 3 JUN 2009
DOI: 10.1002/anie.200901275
Copyright © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Kim, Y., Zhao, H. and Gabbaï, François P. (2009), Sulfonium Boranes for the Selective Capture of Cyanide Ions in Water. Angew. Chem. Int. Ed., 48: 4957–4960. doi: 10.1002/anie.200901275
- †
Publication History
- Issue published online: 17 JUN 2009
- Article first published online: 3 JUN 2009
- Manuscript Received: 16 APR 2009
Funded by
- National Science Foundation. Grant Number: CHE-0646916
- Welch Foundation. Grant Number: A-1423
- US Army Medical Research Institute of Chemical Defense
- 1, , , Perkin Trans. 2 1981, 1554–1557; , , , , J. Am. Chem. Soc. 1983, 105, 6965–6966; , , Acta Crystallogr. Sect. B 1985, 41, 445–452;, , , , J. Am. Chem. Soc. 1986, 108, 6320–6327; , , , , , , , J. Mol. Struct. 1994, 318, 161–169; , , Z. Anorg. Allg. Chem. 1992, 615, 117–122.Direct Link:Direct Link:
- 2, Inclusion Compd. 1991, 4, 391–405; , , , Eur. J. Inorg. Chem. 2000, 2131–2142;, Angew. Chem. 2003, 115, 2318–2321;Direct Link:Angew. Chem. Int. Ed. 2003, 42, 2218–2221.Direct Link:
- 3, , , J. Chem. Soc. Chem. Commun. 1995, 333–334; , , J. Am. Chem. Soc. 2009, 131, 3363–3369; , , , , , , Inorg. Chem. 2008, 47, 793–804; , , , , , J. Am. Chem. Soc. 2008, 130, 10890–10891; , , , , , , , Inorg. Chem. 2008, 47, 9256–9264; , , Dalton Trans. 2008, 814–817; , , , , Chem. Commun. 2007, 2154–2156; , , Inorg. Chem. 2007, 46, 8132–8138; , , , , , , , Dalton Trans. 2007, 3407–3414; , , , , , Chem. Commun. 2007, 1133–1135; , , , , , Chem. Lett. 2007, 36, 976–977; , , , Inorg. Chem. 2006, 45, 9137–9144; , , J. Am. Chem. Soc. 2006, 128, 14248–14249; , , , , Chem. Eur. J. 2009, 15, 5056–5062.Direct Link:
- 4
- 5
- 6
- 7, , Angew. Chem. 2002, 114, 3051–3056;Angew. Chem. Int. Ed. 2002, 41, 2927–2931; , , Chem. Mater. 2004, 16, 4574–4585; , , Pure Appl. Chem. 2006, 78, 1413–1424; , , Angew. Chem. 2008, 120, 846–850;Direct Link:Angew. Chem. Int. Ed. 2008, 47, 834–838.Direct Link:
- 8, , , , , J. Am. Chem. Soc. 2002, 124, 1897–1901.
- 9Crystal data:[1][OTf]-(CH2Cl2)0.5: 0.20×0.10×0.10 mm, C31.5H35BClF3O3S2, Mr=628.98, triclinic, space group P
, a=8.5182(17), b=10.144(2), c=18.638(4) Å, b=92.55(3)°, V=1513.0(5) Å3, Z=2, rcalcd=1.381 Mg m−3, MoKα radiation (l=0.71073 Å), T=110(2) K, 13 329 measured reflections, 4735 unique, Rint=0.0228, R1=0.0508, wR2=0.1268 (all data). [2][OTf]: 0.35×0.13×0.13 mm, C27H32BF3O3S2, Mr=536.46, monoclinic, space group P21/c, a=8.5100(17), b=23.287(5), c=13.710(3) Å, b=99.22(3)°, V=2681.8(9) Å3, Z=4, rcalcd=1.329 Mg m−3, MoKα radiation (l=0.71073 Å), T=110(2) K, 61 457 measured reflections, 6455 unique, Rint=0.0322, R1=0.0532, wR2=0.1258 (all data). 2-CN: 0.31×0.08×0.05 mm, C27H32BNS, Mr=413.41, monoclinic, space group P21/c, a=8.6248(17), b=14.589(3), c=18.030(4) Å, b=96.42(3)°, V=2254.5(8) Å3, Z=4, rcalcd=1.218 Mg m−3, MoKa radiation (l=0.71073 Å), T=110(2) K, 21 259 measured reflections, 5433 unique, Rint=0.0898, R1=0.1361, wR2=0.1696 (all data). Specimens of suitable size and quality were selected and mounted onto 0.7 mm nylon loop with apiezon grease. The structures were solved by direct methods, which successfully located most of the non-hydrogen atoms. Subsequent refinement on F2 using the SHELXTL/PC package (version 5.1) allowed location of the remaining non-hydrogen atoms. CCDC 722717 ([1]+), 722718 ([2]+), and 722719 ([2(CN)]) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif. - 10
- 11, , J. Am. Chem. Soc. 2007, 129, 11978–11986; , , , J. Am. Chem. Soc. 2006, 128, 12879–12885.
- 12
- 13
- 14
- 15Official Journal of the European Communities 1998, L 300, 32–54.
- 16EPA National Primary Drinking Water Standards 2003, see http://www.epa.gov/safewater/contaminants/index.html for more information.
- 17, , Inorg. Chem. 2009, 48, 1272–1274; , , , Analyst 2009, 134, 107–113; , , , , , Chem. Commun. 2008, 1998–2000; , , , J. Am. Chem. Soc. 2008, 130, 12163–12167; , , , , Inorg. Chem. Commun. 2006, 9, 1239–1242; , , , , Chem. Commun. 2008, 5848–5850; , , , , , , , Org. Biomol. Chem. 2008, 6, 3038–3040; , , Org. Lett. 2005, 7, 4633–4636; , , , J. Am. Chem. Soc. 2005, 127, 3635–3641.