Communication

Enantioselective Linchpin Catalysis by SOMO Catalysis: An Approach to the Asymmetric α-Chlorination of Aldehydes and Terminal Epoxide Formation†

  1. Muriel Amatore Dr.,
  2. Teresa D. Beeson,
  3. Sean P. Brown,
  4. David W. C. MacMillan Prof.

Article first published online: 12 JUN 2009

DOI: 10.1002/anie.200901855

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 48, Issue 28, pages 5121–5124, June 29, 2009

Additional Information

How to Cite

Amatore, M., Beeson, Teresa D., Brown, Sean P. and MacMillan, David W. C. (2009), Enantioselective Linchpin Catalysis by SOMO Catalysis: An Approach to the Asymmetric α-Chlorination of Aldehydes and Terminal Epoxide Formation. Angew. Chem. Int. Ed., 48: 5121–5124. doi: 10.1002/anie.200901855

Author Information

  1. Merck Center for Catalysis at Princeton University, Washington Road, Princeton NJ 08544-1009 (USA), Fax: (+1) 609-258-5922 http://www.princeton.edu/∼dmacgr/

  1. †

    Financial support was provided by the NIHGMS (R01 GM078201-01-01), the French Ministry of Foreign Affairs (EGIDE, Lavoisier fellowship for M.A.), Merck and Amgen. The would like to thank J. W. L. Hammett for help with the described racemization studies. SOMO=singly occupied molecular orbital.

Publication History

  1. Issue published online: 25 JUN 2009
  2. Article first published online: 12 JUN 2009
  3. Manuscript Received: 6 APR 2009

Funded by

  • NIHGMS. Grant Number: R01 GM078201-01-01
  • French Ministry of Foreign Affairs
  • Merck
  • Amgen

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