Communication

In Situ Time-Resolved Neutron Diffraction Investigation during Oxygen Exchange in Layered Cobaltite Cathode Materials†

  1. Lorenzo Malavasi Dr.1,
  2. Cristina Tealdi Dr.1,
  3. Clemens Ritter Dr.2

Article first published online: 1 OCT 2009

DOI: 10.1002/anie.200902622

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 48, Issue 45, pages 8539–8542, October 26, 2009

Additional Information

How to Cite

Malavasi, L., Tealdi, C. and Ritter, C. (2009), In Situ Time-Resolved Neutron Diffraction Investigation during Oxygen Exchange in Layered Cobaltite Cathode Materials. Angew. Chem. Int. Ed., 48: 8539–8542. doi: 10.1002/anie.200902622

Author Information

  1. 1

    Department of Physical Chemistry “M. Rolla”, IENI-CNR and INSTM—University of Pavia, Viale Taramelli 16, 27100 Pavia (Italy), Fax: (+39) 0382-987-575

  2. 2

    Institute Laue-Langevin, Boite Postale 156, 38042 Grenoble (France)

  1. †

    The ILL Facility is acknowledged for providing beam time.

Publication History

  1. Issue published online: 20 OCT 2009
  2. Article first published online: 1 OCT 2009
  3. Manuscript Revised: 8 JUL 2009
  4. Manuscript Received: 16 MAY 2009

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Keywords:

  • fuel cells;
  • oxygen exchange;
  • solid-state structures;
  • time-resolved neutron diffraction
Thumbnail image of graphical abstract

Keep your eye on the oxygen: In situ time-resolved neutron diffraction measurements can be used to study the structural changes occurring during oxygen exchange in a material (see graph of the increase in oxygen content when the gas flux is switched from Ar to O2). The method is demonstrated for a layered cobaltite, which is a promising cathode material for intermediate-temperature fuel cells.

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