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Keywords:

  • amine–boranes;
  • catalysis;
  • dehydrogenation;
  • rhodium;
  • structure elucidation
Thumbnail image of graphical abstract

Getting a fix: Bis(σ-amine–borane) rhodium complexes featuring a new binding mode (two amine–borane ligands) have been prepared (see picture; Rh yellow, P green, B pink, N blue). These complexes undergo dehydrocoupling to afford di- or trimeric cyclic aminoboryl products.