Communication

Breathing Transitions in MIL-53(Al) Metal–Organic Framework Upon Xenon Adsorption

  1. Anne Boutin Dr.2,7,
  2. Marie-Anne Springuel-Huet Dr.3,
  3. Andrei Nossov Dr.3,
  4. Antoine Gédéon Prof. Dr.3,
  5. Thierry Loiseau Dr.4,6,
  6. Christophe Volkringer Dr.4,
  7. Gérard Férey Prof. Dr.4,5,
  8. François-Xavier Coudert Dr.1,
  9. Alain H. Fuchs Prof. Dr.1

Article first published online: 24 SEP 2009

DOI: 10.1002/anie.200903153

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 48, Issue 44, pages 8314–8317, October 19, 2009

Additional Information

How to Cite

Boutin, A., Springuel-Huet, M.-A., Nossov, A., Gédéon, A., Loiseau, T., Volkringer, C., Férey, G., Coudert, F.-X. and Fuchs, A. (2009), Breathing Transitions in MIL-53(Al) Metal–Organic Framework Upon Xenon Adsorption. Angewandte Chemie International Edition, 48: 8314–8317. doi: 10.1002/anie.200903153

Author Information

  1. 1

    Ecole nationale supérieure de chimie de Paris (Chimie ParisTech), CNRS and Univ. Pierre et Marie Curie, 11, rue Pierre et Marie Curie, 75005 Paris (France), Fax: (+33) 1-4329-2059

  2. 2

    Laboratoire de Chimie Physique, CNRS and Univ. Paris-Sud, 91405 Orsay Cedex (France)

  3. 3

    Laboratoire Système Interfaciaux à l'Échelle Nanométrique, Université Pierre et Marie Curie, 75252 Paris Cedex 05 (France)

  4. 4

    Institut Lavoisier, UMR CNRS 8180 and Université de Versailles, St-Quentin en Yvelines, 78035 Versailles (France)

  5. 5

    Institut Universitaire de France, Paris (France)

  6. 6

    Present address: Unité de Catalyse et de Chimie du Solide, USTL-ENSCL, 59652 Villeneuve d'Ascq (France)

  7. 7

    Present address: Chemistry Department, Ecole normale supérieure 75005 Paris (France)

Publication History

  1. Issue published online: 13 OCT 2009
  2. Article first published online: 24 SEP 2009
  3. Manuscript Revised: 10 AUG 2009
  4. Manuscript Received: 11 JUN 2009

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Keywords:

  • adsorption;
  • metal–organic frameworks;
  • nanoporous materials;
  • thermodynamics;
  • xenon

Graphical Abstract

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MOFs come alive: The combination of gas-adsorption experiments at various temperatures with an osmotic thermodynamic model produced a generic temperature–loading phase diagram that displays unexpected re-entrant behavior. The breathing effect in the metal–organic framework MIL-53(Al) is predicted to be general and should be observed over a limited temperature range regardless of the guest adsorbate.

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