Communication

Trifluoromethanesulfanylamides as Easy-to-Handle Equivalents of the Trifluoromethanesulfanyl Cation (CF3S+): Reaction with Alkenes and Alkynes†

  1. Aurélien Ferry Dr.1,
  2. Thierry Billard Dr.1,
  3. Bernard R. Langlois Dr.1,
  4. Eric Bacqué Dr.2

Article first published online: 6 OCT 2009

DOI: 10.1002/anie.200903387

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 48, Issue 45, pages 8551–8555, October 26, 2009

Additional Information

How to Cite

Ferry, A., Billard, T., Langlois, Bernard R. and Bacqué, E. (2009), Trifluoromethanesulfanylamides as Easy-to-Handle Equivalents of the Trifluoromethanesulfanyl Cation (CF3S+): Reaction with Alkenes and Alkynes. Angew. Chem. Int. Ed., 48: 8551–8555. doi: 10.1002/anie.200903387

Author Information

  1. 1

    Université de Lyon, Université Lyon 1, CNRS ICBMS (UMR CNRS 5246)—Laboratoire SERCOF, 43 Bd du 11 novembre 1918, Bat Chevreul, 69622 Villeurbanne (France), Fax: (+33) 4-7243-1323

  2. 2

    Sanofi-Aventis S.A. 136, Quai Jules Guesde, BP 14, 94403 Vitry-Sur-Seine Cedex (France)

  1. †

    We thank the CNRS and the Sanofi-Aventis Co. for financial support.

Publication History

  1. Issue published online: 20 OCT 2009
  2. Article first published online: 6 OCT 2009
  3. Manuscript Revised: 20 JUL 2009
  4. Manuscript Received: 23 JUN 2009

Funded by

  • CNRS

SEARCH

SEARCH BY CITATION

ARTICLE TOOLS

View Full Article with Supporting Information (HTML) Get PDF (331K)

Keywords:

  • alkenes;
  • alkynes;
  • electrophilic addition;
  • fluorine;
  • trifluoromethanesulfanylamides
Thumbnail image of graphical abstract

Making introductions: The CF3S unit can be added in an electrophilic fashion to alkenes and alkynes in reactions with trifluoromethanesulfanylamide reagents (see scheme; Ts=toluene-4-sulfonyl). The products obtained may be of interest, for example, in pharmaceutical chemistry and materials science.

View Full Article with Supporting Information (HTML) Get PDF (331K)