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High-Oxidation-State Palladium Catalysis: New Reactivity for Organic Synthesis
Article first published online: 30 OCT 2009
DOI: 10.1002/anie.200903671
Copyright © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Muñiz, K. (2009), High-Oxidation-State Palladium Catalysis: New Reactivity for Organic Synthesis. Angew. Chem. Int. Ed., 48: 9412–9423. doi: 10.1002/anie.200903671
Publication History
- Issue published online: 30 NOV 2009
- Article first published online: 30 OCT 2009
- Manuscript Received: 5 JUL 2009
Funded by
- Fonds der Chemischen Industrie
- Institut Universitaire de France
- Abstract
- Article
- References
- Cited By
Keywords:
- coupling reactions;
- elimination;
- homogeneous catalysis;
- oxidation states;
- palladium
Abstract
Recent years have seen the rapid development of a new field of palladium catalysis in organic synthesis. This chemistry takes place outside the usually encountered Pd0/PdII cycles. It is characterized by the presence of strong oxidants, which prevent further palladium(II)-promoted reactions at a given point of the catalytic cycle by selective metal oxidation. The resulting higher-oxidation-state palladium complexes have been used to develop a series of new synthetic transformations that cannnot be realized within conventional palladium catalysis. This type of catalysis by palladium in a higher oxidation state is of significant synthetic potential.