We are grateful to the Academia Sinica and the National Science Council, Taiwan for financial support of this research.
Communication
Self-Assembled Arrays of Single-Walled Metal–Organic Nanotubes†
Article first published online: 10 NOV 2009
DOI: 10.1002/anie.200904501
Copyright © 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Additional Information
How to Cite
Luo, T.-T., Wu, H.-C., Jao, Y.-C., Huang, S.-M., Tseng, T.-W., Wen, Y.-S., Lee, G.-H., Peng, S.-M. and Lu, K.-L. (2009), Self-Assembled Arrays of Single-Walled Metal–Organic Nanotubes. Angew. Chem. Int. Ed., 48: 9461–9464. doi: 10.1002/anie.200904501
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Publication History
- Issue published online: 30 NOV 2009
- Article first published online: 10 NOV 2009
- Manuscript Received: 12 AUG 2009
Funded by
- Academia Sinica
- National Science Council, Taiwan
Keywords:
- crystal engineering;
- microporous materials;
- nanotubes;
- self-assembly;
- topochemistry

Dragon's lair: A large, single-walled metal–organic nanotube (MONT) with an exterior diameter of up to 3.2 nm and an internal channel diameter of 1.4 nm is presented. The tube can be depicted as hexastranded helices consisting of three right-handed and three left-handed helical chains, and resembles a rolled-up dragon column (see picture). The MONTs are held together by alkaline ions to form unique nanotubular arrays.

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