Communication

Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area†

  1. Teng Ben1,
  2. Hao Ren1,
  3. Shengqian Ma2,
  4. Dapeng Cao Prof.3,
  5. Jianhui Lan3,
  6. Xiaofei Jing1,
  7. Wenchuan Wang Prof.3,
  8. Jun Xu4,
  9. Feng Deng Prof.4,
  10. Jason M. Simmons Prof.5,
  11. Shilun Qiu Prof.1,
  12. Guangshan Zhu Prof.1

Article first published online: 17 NOV 2009

DOI: 10.1002/anie.200904637

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 48, Issue 50, pages 9457–9460, December 7, 2009

Additional Information

How to Cite

Ben, T., Ren, H., Ma, S., Cao, D., Lan, J., Jing, X., Wang, W., Xu, J., Deng, F., Simmons, Jason M., Qiu, S. and Zhu, G. (2009), Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area. Angew. Chem. Int. Ed., 48: 9457–9460. doi: 10.1002/anie.200904637

Author Information

  1. 1

    State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun (China), Fax: (+86) 431-8516-8331

  2. 2

    Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439 (USA)

  3. 3

    Key Lab for Nanomaterials, Beijing University of Chemical Technology, Beijing (China)

  4. 4

    State Key Lab of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Wuhan (China)

  5. 5

    NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, MD 20899-8562 (USA)

  1. †

    The study was supported by the Outstanding Young Scientist Foundation of the NSFC (20625102), the International Science and Technology Cooperation Program (2007DFA40830), the State Basic Research Project (2006CB806100), NSFC, the “111” Program of Ministry of Education and the Jilin Province Hi-Tech Development Project. S.M. acknowledges the Director’s Postdoctoral Fellowship from the Argonne National Laboratory. J.M.S. acknowledges support from the National Research Council Research Associates Program and the U.S. Department of Energy.

Publication History

  1. Issue published online: 30 NOV 2009
  2. Article first published online: 17 NOV 2009
  3. Manuscript Received: 20 AUG 2009

Funded by

  • NSFC. Grant Number: 20625102
  • International Science and Technology Cooperation Program. Grant Number: 2007DFA40830
  • State Basic Research Project. Grant Number: 2006CB806100
  • NSFC
  • Ministry of Education
  • Jilin Province Hi-Tech Development Project
  • National Research Council Research Associates Program
  • U.S. Department of Energy

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Keywords:

  • adsorption;
  • carbon dioxide;
  • hydrogen;
  • organic frameworks;
  • porous materials
Thumbnail image of graphical abstract

Diamonds are forever: A diamond-like framework in which the C–C bonds are replaced with rigid phenyl rings (see picture) is not only structurally stable but also has a large internal surface area. This porous aromatic framework (PAF-1) demonstrates high uptake capacities of hydrogen and carbon dioxide as well as benzene and toluene vapors, and has an unprecedented surface area of 7100 m2 g−1.

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