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Keywords:

  • B[BOND]H activation;
  • boranes;
  • oxidative addition;
  • rhodium;
  • X-ray diffraction
Thumbnail image of graphical abstract

The missing link: A bimetallic complex that is relevant to the mechanism of transition-metal-catalyzed amine–borane dehydrocoupling has been isolated. The structure (see picture) contains three different amine–borane activation modes within the same molecule.