Inside Cover

Inside Cover: Stable Pentavalent Uranyl Species and Selective Assembly of a Polymetallic Mixed-Valent Uranyl Complex by Cation–Cation Interactions (Angew. Chem. Int. Ed. 45/2009)

  1. Victor Mougel,
  2. Pawel Horeglad Dr.,
  3. Grégory Nocton,
  4. Jacques Pécaut Dr.,
  5. Marinella Mazzanti Dr.

Article first published online: 6 OCT 2009

DOI: 10.1002/anie.200905187

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 48, Issue 45, page 8382, October 26, 2009

Additional Information

How to Cite

Mougel, V., Horeglad, P., Nocton, G., Pécaut, J. and Mazzanti, M. (2009), Inside Cover: Stable Pentavalent Uranyl Species and Selective Assembly of a Polymetallic Mixed-Valent Uranyl Complex by Cation–Cation Interactions (Angew. Chem. Int. Ed. 45/2009). Angew. Chem. Int. Ed., 48: 8382. doi: 10.1002/anie.200905187

Author Information

  1. Laboratoire de Reconnaissance Ionique et Chimie de Coordination, Service de Chimie Inorganique et Biologique, UMR E-3 CEA/UJF, FRE3200 CNRS, CEA-Grenoble, INAC, 17 rue des Martyrs, 38054 Grenoble Cedex 9 (France), Fax: (+33) 4-3878-5090

Publication History

  1. Issue published online: 20 OCT 2009
  2. Article first published online: 6 OCT 2009

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Keywords:

  • actinides;
  • cation–cation interactions;
  • cluster compounds;
  • self-assembly;
  • uranium
Thumbnail image of graphical abstract

Oligomeric cation–cation complexes of actinyls are highly relevant for nuclear waste reprocessing and the migration of actinides in the environment. In their Communication on page 8477 ff., M. Mazzanti et al. show that the N,N′-bis(salicylidene)ethylenediamine (salen) ligand can stabilize uranium in the pentavalent state. A tetrametallic cation–cation complex shows stability towards disproportionation and hydrolysis, and an unambiguous antiferromagnetic coupling between the four oxo-bridged uranium centers.

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