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Synthesis and Coordination Properties of Nitrogen(I)-Based Ligands

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  • We thank Prof. A. Fürstner for generous support and constant encouragement. Financial support from the Max Planck-Institut für Kohlenforschung is also gratefully acknowledged.

Abstract

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Give me four: In contrast to typical imines, the central nitrogen atom in cyclopropenyl-derived carbeneimines (see example; C gray, N blue) can donate up to four electrons to form coordination complexes.

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