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Directed Orthogonal Self-Assembly of Homochiral Coordination Polymers for Heterogeneous Enantioselective Hydrogenation

Authors

  • Liting Yu,

    1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032 (P. R. China), Fax: (86) 21-6416-6128
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  • Zheng Wang Dr.,

    1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032 (P. R. China), Fax: (86) 21-6416-6128
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  • Jiang Wu,

    1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032 (P. R. China), Fax: (86) 21-6416-6128
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  • Shujiang Tu Prof. Dr.,

    1. College of Chemistry and Chemical Engineering, Xuzhou Normal University, Xuzhou, Jiangsu 221116 (P. R. China)
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  • Kuiling Ding Prof. Dr.

    1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032 (P. R. China), Fax: (86) 21-6416-6128
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  • Financial support from the National Natural Science Foundation of China (Nos. 20632060, 20821002), the Chinese Academy of Sciences, the Major Basic Research Development Program of China (Grant Nos. 2010CB833300, 2006CB806106), the Science and Technology Commission of Shanghai Municipality, and Merck Research Laboratories is gratefully acknowledged.

Abstract

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Three in one: Orthogonal coordination of FeII and RhI with a single heteroditopic ligand results in the formation of self-supported heterogeneous chiral catalysts (see scheme). The compounds are highly active, enantioselective, and reusable in the heterogeneous asymmetric hydrogenation of various functionalized olefin derivatives.

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