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Gold-Catalyzed Halogenation of Aromatics by N-Halosuccinimides

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  • The project is supported by the NSFC (Grant No. 20832002, 20772003, 20821062), 973 Program (No. 2009CB825300).

Abstract

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Golden bromination: A highly efficient and mild AuCl3-catalyzed bromination of aromatic rings with N-bromosuccinimide (NBS) has been developed. This method works with a low catalyst loading (down to 0.01 mol %) and can be combined with transition metal catalyzed transformations to deliver various aryl products.

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