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Keywords:

  • axinellamines;
  • massadine;
  • palau’amine;
  • total synthesis
Thumbnail image of graphical abstract

Worth the wait: The long anticipated total synthesis of palau'amine has been accomplished by a route featuring highly chemoselective transformations, cascade reactions, and a remarkable transannular cyclization to secure the unprecedented trans-5,5 ring junction (shown in red).