Cover Picture: Heterogeneously Hybridized Porous Coordination Polymer Crystals: Fabrication of Heterometallic Core–Shell Single Crystals with an In-Plane Rotational Epitaxial Relationship (Angew. Chem. Int. Ed. 10/2009)

  1. Shuhei Furukawa Dr.1,2,
  2. Kenji Hirai3,
  3. Keiji Nakagawa3,
  4. Yohei Takashima3,
  5. Ryotaro Matsuda Dr.1,2,
  6. Takaaki Tsuruoka Dr.1,
  7. Mio Kondo Dr.2,
  8. Rie Haruki Dr.4,
  9. Daisuke Tanaka Dr.3,
  10. Hirotoshi Sakamoto3,
  11. Satoru Shimomura3,
  12. Osami Sakata Dr.4,
  13. Susumu Kitagawa Prof.1,2,3

Article first published online: 17 FEB 2009

DOI: 10.1002/anie.200990041

Issue

Angewandte Chemie International Edition

Angewandte Chemie International Edition

Volume 48, Issue 10, page 1697, February 23, 2009

Additional Information

How to Cite

Furukawa, S., Hirai, K., Nakagawa, K., Takashima, Y., Matsuda, R., Tsuruoka, T., Kondo, M., Haruki, R., Tanaka, D., Sakamoto, H., Shimomura, S., Sakata, O. and Kitagawa, S. (2009), Cover Picture: Heterogeneously Hybridized Porous Coordination Polymer Crystals: Fabrication of Heterometallic Core–Shell Single Crystals with an In-Plane Rotational Epitaxial Relationship (Angew. Chem. Int. Ed. 10/2009). Angew. Chem. Int. Ed., 48: 1697. doi: 10.1002/anie.200990041

Author Information

  1. 1

    ERATO Kitagawa Integrated Pores Project (Japan), Kyoto Research Park Bldg #3, Shimogyo-ku, Kyoto 600-8815 (Japan), Fax: (+81) 75-325-3572 http://kip.jst.go.jp

  2. 2

    Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501 (Japan)

  3. 3

    Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)

  4. 4

    Research & Utilization Division (Japan), Synchrotron Radiation Research Institute/SPring-8 and CREST, JST, Kouto, Sayo, Hyogo 679-5198 (Japan)

Publication History

  1. Issue published online: 17 FEB 2009
  2. Article first published online: 17 FEB 2009

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Keywords:

  • coordination polymers;
  • crystal growth;
  • interfaces;
  • metal–organic frameworks;
  • microporous materials

Abstract

Thumbnail image of graphical abstract

A porous copper coordination framework grew epitaxially as a single crystal on the surface of a single crystal of a porous zinc coordination framework, as described by S. Kitagawa and co-workers in their Communication on page 1766 ff. The picture shows the structural relationship between the copper and zinc frameworks, which has been unveiled by synchrotron surface X-ray diffraction measurements; in-plane rotational epitaxial growth compensates for the different lattice constants of the two crystals.

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