Ionothermal Synthesis of an Aluminophosphate Molecular Sieve with 20-Ring Pore Openings

Authors

  • Ying Wei,

    1. State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China), Fax: (+86) 411-843-79151
    2. Graduate School of Chinese Academy of Sciences, Beijing 100049 (China)
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  • Zhijian Tian Prof.,

    1. State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China), Fax: (+86) 411-843-79151
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  • Hermann Gies Prof.,

    1. Institute for Geology, Mineralogy and Geophysics, Ruhr University, 44780 Bochum (Germany)
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  • Renshun Xu,

    1. State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China), Fax: (+86) 411-843-79151
    2. Graduate School of Chinese Academy of Sciences, Beijing 100049 (China)
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  • Huaijun Ma Dr.,

    1. State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China), Fax: (+86) 411-843-79151
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  • Renyan Pei,

    1. State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China), Fax: (+86) 411-843-79151
    2. Graduate School of Chinese Academy of Sciences, Beijing 100049 (China)
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  • Weiping Zhang Prof.,

    1. State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China), Fax: (+86) 411-843-79151
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  • Yunpeng Xu Prof.,

    1. State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China), Fax: (+86) 411-843-79151
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  • Lei Wang Dr.,

    1. State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China), Fax: (+86) 411-843-79151
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  • Keda Li,

    1. State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China), Fax: (+86) 411-843-79151
    2. Graduate School of Chinese Academy of Sciences, Beijing 100049 (China)
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  • Bingchun Wang Dr.,

    1. State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China), Fax: (+86) 411-843-79151
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  • Guodong Wen,

    1. State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China), Fax: (+86) 411-843-79151
    2. Graduate School of Chinese Academy of Sciences, Beijing 100049 (China)
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  • Liwu Lin Prof.

    1. State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China), Fax: (+86) 411-843-79151
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  • This work was supported by the National Natural Science Foundation of China (grant no. 20903092).

Abstract

original image

Open for business: The first aluminophosphate molecular sieve with 20-ring pore openings has been synthesized ionothermally using a co-structure-directing agent (see figure; H white, C turquoise, N blue). The new material has a -CLO framework and excellent stability in comparison to the GaPO4 analogue cloverite. These characteristics indicate its potential applications in separation, catalysis, and gas storage.

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