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Coordinatively Immobilized Monolayers on Porous Coordination Polymer Crystals

Authors

  • Mio Kondo Dr.,

    1. Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501 (Japan)
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  • Shuhei Furukawa Dr.,

    1. Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501 (Japan)
    2. ERATO Kitagawa Integrated Pores Project, Japan Science and Technology Agency (JST), Kyoto Research Park Bldg #3, Shimogyo-ku, Kyoto 600-8815 (Japan)
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  • Kenji Hirai,

    1. Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
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  • Susumu Kitagawa Prof.

    1. Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501 (Japan)
    2. ERATO Kitagawa Integrated Pores Project, Japan Science and Technology Agency (JST), Kyoto Research Park Bldg #3, Shimogyo-ku, Kyoto 600-8815 (Japan)
    3. Department of Synthetic Chemistry & Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)
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  • M.K. is grateful to JSPS Research Fellowships for Young Scientists. This work was supported by Grants-in-Aid for Young Scientists (B) from MEXT (Japan) (20750106). We acknowledge Y. Kinoshita, Dr. R. Matsuda, Dr. M. Higuchi, and Dr. R. Kitaura for their preliminary studies, and Dr. C. Bonneau for fruitful discussions.

Abstract

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Surface-specific: Coordinatively immobilized monolayers (CIMs) of fluorescent dyes were fabricated on specific single-crystal surfaces of porous coordination polymers (PCPs) (see picture). This approach enables the fabrication of functional PCP crystal surfaces with precisely controlled fluorescent gating and sensing properties.

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