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Long-Lived Radical Cations of Monocyclic Arenes at Room Temperature Obtained by NbF5 Acting as an Oxidizing Agent and Counterion Precursor


  • We thank the Ministero dell’Istruzione, dell’Università e della Ricerca (MIUR, Roma) and the Programma di Ricerca Scientifica di Notevole Interesse Nazionale for financial support.


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Salt of the earth: Radical cation salts of monocyclic arenes, including benzene, have been obtained in a reaction where niobium pentafluoride behaves both as an oxidizing agent (conversion into NbF4) and fluoride acceptor (to afford the counterion [Nb2F11], see picture). Anion–π-electron density interactions, as revealed by experimental and computational studies, are crucial in providing unprecedented inertness to the radical cations.