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Keywords:

  • carbon dioxide;
  • coordination polymers;
  • host–guest systems;
  • hybrid materials;
  • phase transitions
Thumbnail image of graphical abstract

Transforming jungle gyms: Structural flexibility and sorption behavior can be tuned by controlling the degree of interpenetration of 3D porous coordination polymers (PCPs). The architectural connectivity of PCPs, even those that are composed of the same chemical components, has a significant impact on the structural flexibility and sorption behavior, which was confirmed by coincident XRPD/adsorption measurements.